1.2 Relevant identified uses of the substance or mixture and uses advised against

SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product Identifier Material Name : Product Code : 001D Relevant identified uses of the substance or mixture
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SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Product Identifier Material Name : Product Code : 001D Relevant identified uses of the substance or mixture and uses advised against Product Use : Transmission oil. Uses Advised Against : This product must not be used in applications other than those recommended in Section 1, without first seeking the advice of the supplier. 1.3 Details of the Supplier of the safety data sheet Manufacturer/Supplier : Shell UK Oil Products Limited Shell Centre London SE1 7NA United Kingdom Telephone : (+44) Contact for : If you have any enquiries about the content of this SDS please Safety Data Sheet 1.4 Emergency Telephone Number : +44-(0) SECTION 2. HAZARDS IDENTIFICATION 2.1 Classification of the substance or mixture 67/548/EEC or 1999/45/EC Hazard Characteristics R-phrase(s) Dangerous for the environment.; R52/ Label Elements 1/18 Labeling according to Directive 1999/45/EC EC Symbols : No Hazard Symbol required EC Classification : Dangerous for the environment. EC Risk Phrases : R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. EC Safety Phrases : S61 Avoid release to the environment. Refer to special instructions/safety data sheets. 2.3 Other Hazards Health Hazards : Not expected to be a health hazard when used under normal conditions. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Used oil may contain harmful impurities. Safety Hazards : Not classified as flammable but will burn. Environmental Hazards : Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Substance Material Name : Not applicable. 3.2 Mixtures Mixture Description : Blend of severely hydrotreated slack wax, synthetic esters, polyolefins and additives. Highly refined mineral oil. Hazardous Components Classification of components according to Regulation (EC) No 1272/2008 Chemical Name CAS No. EC Number REACH Registration No. Alkyl phosphonate Not available Not available Not available / Not applicable. Conc % 2/18 Alkyl dithiophosphate Not available Not available Not available / Not % applicable. Long-chain alkenyl Not available Not available Not available / Not % amine applicable. Interchangeable low viscosity base oil ( 20,5 C) * * * * % Chemical Name Hazard Class & Category Hazard Statement Alkyl phosphonate Skin Corr., 2; Eye Dam., 1; Aquatic H315; H318; H411; Chronic, 2; Alkyl dithiophosphate Eye Dam., 2; Aquatic Chronic, 1; H319; H410; Long-chain alkenyl Acute Tox., 4; Skin Corr., 1A; Aquatic H302; H314; H400; amine Acute, 1; Interchangeable low viscosity base oil ( 20,5 C) * Asp. Tox., 1; H304; Classification of components according to 67/548/EEC Chemical Name CAS No. EC Number Alkyl phosphonate Alkyl dithiophosphate Long-chain alkenyl amine Not available Not available Not available Not available Not available Not available REACH Registration No. Not available / Not applicable. Not available / Not applicable. Not available / Not applicable. Symbol(s) R-phrase(s) Conc. Xi, N R38; R41; R51/ % Xi, N R36; R50/ % C, Xn, N R22; R35; R % Additional Information : The highly refined mineral oil contains 3% (w/w) DMSOextract, according to IP346. The highly refined mineral oil is only present as additive diluent. Refer to Ch 16 for full text of R- and H- phrases. This mixture does not contain any REACH registered substances that are assessed to be a PBT or a vpvb. * contains one or more of the following CAS-numbers (REACH registration numbers): ( ), /18 SECTION 4. FIRST-AID MEASURES 4.1 Description of First Aid Measures 54-7 ( ), ( ), ( ), ( ), ( ), ( ), ( ), ( ), ( ). General Information : Not expected to be a health hazard when used under normal conditions. Inhalation : No treatment necessary under normal conditions of use. If symptoms persist, obtain medical advice. Skin Contact : Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. Eye Contact : Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. Ingestion : In general no treatment is necessary unless large quantities are swallowed, however, get medical advice. Self-protection of the first aider 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed SECTION 5. FIRE-FIGHTING MEASURES : When administering first aid, ensure that you are wearing the appropriate personal protective equipment according to the incident, injury and surroundings. : Oil acne/folliculitis signs and symptoms may include formation of black pustules and spots on the skin of exposed areas. Ingestion may result in nausea, vomiting and/or diarrhoea. : Notes to doctor/physician: Treat symptomatically. Clear fire area of all non-emergency personnel. 5.1 Extinguishing Media : Foam, water spray or fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable Extinguishing : Do not use water in a jet. Media 5.2 Special hazards arising from the substance or mixture : Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide may be evolved if incomplete combustion occurs. Unidentified organic and inorganic 4/18 compounds. 5.3 Advice for firefighters : Proper protective equipment including chemical resistant gloves are to be worn; chemical resistant suit is indicated if large contact with spilled product is expected. Self-Contained Breathing Apparatus must be worn when approaching a fire in a confined space. Select fire fighter's clothing approved to relevant Standards (e.g. Europe: EN469). SECTION 6. ACCIDENTAL RELEASE MEASURES Avoid contact with spilled or released material. For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. Observe the relevant local and international regulations. 6.1 Personal Precautions, Protective Equipment and Emergency Procedures : For non emergency personnel: Avoid contact with skin and eyes For emergency responders: Avoid contact with skin and eyes. 6.2 Environmental Precautions : Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. 6.3 Methods and Material for Containment and Cleaning Up : Slippery when spilt. Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth or other containment material. Reclaim liquid directly or in an absorbent. Soak up residue with an absorbent such as clay, sand or other suitable material and dispose of properly. Additional Advice : Local authorities should be advised if significant spillages cannot be contained. 6.4 Reference to other sections SECTION 7. HANDLING AND STORAGE : For guidance on selection of personal protective equipment see Chapter 8 of this Material Safety Data Sheet. For guidance on disposal of spilled material see Chapter 13 of this Material Safety Data Sheet. General Precautions : Use local exhaust ventilation if there is risk of inhalation of vapours, mists or aerosols. Use the information in this data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. 7.1 Precautions for Safe Handling : Avoid prolonged or repeated contact with skin. Avoid inhaling vapour and/or mists. When handling product in drums, safety 5/18 footwear should be worn and proper handling equipment should be used. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Keep container tightly closed and in a cool, well-ventilated place. Use properly labelled and closeable containers. Product Transfer : This material has the potential to be a static accumulator. Proper grounding and bonding procedures should be used during all bulk transfer operations. 7.2 Conditions for safe storage, including any incompatibilities : Storage Temperature: C / F Refer to section 15 for any additional specific legislation covering the packaging and storage of this product. The storage of this product may be subject to the Control of Pollution (Oil Storage) (England) Regulations. Further guidance may be obtained from the local environmental agency office. Recommended Materials : For containers or container linings, use mild steel or high density polyethylene. Unsuitable Materials : PVC. 7.3 Specific end use(s) : Please refer to Ch16 and/or the annexes for the registered uses under REACH. Additional Information : Polyethylene containers should not be exposed to high temperatures because of possible risk of distortion. Exposure to this product should be reduced as low as reasonably practicable. Reference should be made to the Health and Safety Executive's publication COSHH Essentials . SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION If the American Conference of Governmental Industrial Hygienists (ACGIH) value is provided on this document, it is provided for information only. 8.1 Control Parameters Occupational Exposure Limits Material Source Type ppm mg/m3 Notation Oil mist, mineral ACGIH TWA(Inhala 5 mg/m3 ble fraction.) 6/18 Biological Exposure Index (BEI) No biological limit allocated. PNEC related information : Data not available Monitoring Methods : Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Validated exposure measurement methods should be applied by a competent person and samples analysed by an accredited laboratory. Examples of sources of recommended exposure measurement methods are given below or contact the supplier. Further national methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances Institut für Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA), Germany. L'Institut National de Recherche et de Securité, (INRS), France 8.2 Exposure Controls General Information : The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Adequate ventilation to control airborne concentrations. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. 7/18 Define procedures for safe handling and maintenance of controls. Educate and train workers in the hazards and control measures relevant to normal activities associated with this product. Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.g. personal protective equipment, local exhaust ventilation. Drain down system prior to equipment break-in or maintenance. Retain drain downs in sealed storage pending disposal or for subsequent recycle. Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Occupational Exposure Controls Personal Protective Equipment : The provided information is made in consideration of the PPE directive (Council Directive 89/686/EEC) and the CEN European Committee for Standardisation (CEN) standards. Personal protective equipment (PPE) should meet recommended national standards. Check with PPE suppliers. Eye Protection : Wear safety glasses or full face shield if splashes are likely to occur. Approved to EU Standard EN166. Hand Protection : Where hand contact with the product may occur the use of gloves approved to relevant standards (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection: PVC, neoprene or nitrile rubber gloves. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated gloves should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturizer is recommended. For continuous contact we recommend gloves with breakthrough time of more than 240 minutes with preference for 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognise that suitable gloves offering this level of protection may not be available and in this case a lower breakthrough time may be acceptable so long as appropriate maintenance 8/18 and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material. Glove thickness should be typically greater than 0.35 mm depending on the glove make and model. Body protection : Skin protection not ordinarily required beyond standard issue work clothes. Respiratory Protection : No respiratory protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid breathing of material. If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air-filtering respirators are suitable, select an appropriate combination of mask and filter. Select a filter suitable for combined particulate/organic gases and vapors [Type A/Type P boiling point 65 C (149 F)] meeting EN14387 and EN143. Thermal Hazards : Not applicable. Environmental Exposure Controls Environmental exposure control measures : Take appropriate measures to fulfil the requirements of relevant environmental protection legislation. Avoid contamination of the environment by following advice given in Chapter 6. If necessary, prevent undissolved material from being discharged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before discharge to surface water. Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on basic physical and chemical properties Appearance : Amber. Liquid at room temperature. Odour : Slight hydrocarbon. Odour threshold : Data not available ph : Not applicable. Initial Boiling Point and : 280 C / 536 F estimated value(s) Boiling Range Pour point : Typical -42 C / -44 F Flash point : Typical 210 C / 410 F (COC) 9/18 Upper / lower Flammability : Typical 1-10 %(V) or Explosion limits Auto-ignition temperature : 320 C / 608 F Vapour pressure : 0.5 Pa at 20 C / 68 F (estimated value(s)) Relative Density : Typical at 15 C / 59 F Density : Typical 878 kg/m3 at 15 C / 59 F Water solubility : Negligible. Solubility in other solvents : Data not available n-octanol/water partition : 6 (based on information on similar products) coefficient (log Pow) Dynamic viscosity : Data not available Kinematic viscosity : Typical 115 mm2/s at 40 C / 104 F Vapour density (air=1) : 1 (estimated value(s)) Evaporation rate (nbuac=1) : Data not available Decomposition : Data not available Temperature Flammability : Data not available Oxidizing Properties : Data not available Explosive Properties : Not classified 9.2 Other Information Electrical conductivity : This material is not expected to be a static accumulator. Other Information : not a VOC Volatile organic compound : 0 % SECTION 10. STABILITY AND REACTIVITY 10.1 Reactivity : The product does not pose any further reactivity hazards in addition to those listed in the following sub-paragraph Chemical stability : No hazardous reaction is expected when handled and stored according to provisions Possibility of : Hazardous Reactions Reacts with strong oxidising agents Conditions to Avoid : Extremes of temperature and direct sunlight Incompatible : Strong oxidising agents. Materials 10.6 Hazardous Decomposition Products : Hazardous decomposition products are not expected to form during normal storage. 10/18 SECTION 11. TOXICOLOGICAL INFORMATION 11.1 Information on Toxicological effects Basis for Assessment : Information given is based on data on the components and the toxicology of similar products. Unless indicated otherwise, the data presented is representative of the product as a whole, rather than for individual component(s). Likely Routes of Exposure : Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion. Acute Oral Toxicity : Expected to be of low toxicity: LD50 5000 mg/kg, Rat Acute Dermal Toxicity : Expected to be of low toxicity: LD50 5000 mg/kg, Rabbit Acute Inhalation Toxicity : Not considered to be an inhalation hazard under normal conditions of use. Low toxicity by inhalation. Skin corrosion/irritation : Expected to be slightly irritating. Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis. Serious eye : Expected to be slightly irritating. damage/irritation Respiratory Irritation : Inhalation of vapours or mists may cause irritation. Respiratory or skin sensitisation : For respiratory and skin sensitisation: Not expected to be a sensitiser. Aspiration Hazard : Not considered an aspiration hazard. Germ cell mutagenicity : Not considered a mutagenic hazard. Carcinogenicity : Not expected to be carcinogenic. Material : Carcinogenicity Classification Highly refined mineral oil : ACGIH Group A4: Not classifiable as a human carcinogen. (IP346 3%) Highly refined mineral oil : IARC 3: Not classifiable as to carcinogenicity to humans. (IP346 3%) Highly refined mineral oil (IP346 3%) : GHS / CLP: No carcinogenicity classification Reproductive and Developmental Toxicity : Not expected to be a hazard. Summary on evaluation of the CMR properties Carcinogenicity : This product does not meet the criteria for classification in categories 1A/1B., Mutagenicity : This product does not meet the criteria for classification in 11/18 Reproductive Toxicity (fertility) categories 1A/1B. : This product does not meet the criteria for classification in categories 1A/1B. Specific target organ : Not expected to be a hazard. toxicity - single exposure Specific target organ : Not expected to be a hazard. toxicity - repeated exposure Additional Information : Used oils may contain harmful impurities that have accumulated during use. The concentration of such impurities will depend on use and they may present risks to health and the environment on disposal. ALL used oil should be handled with caution and skin contact avoided as far as possible. Classifications by other authorities under varying regulatory frameworks may exist. SECTION 12. ECOLOGICAL INFORMATION Basis for Assessment : Ecotoxicological data have not been determined specifically for this prod
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